n-Pentane 99.99% for HPLC & Spectroscopy 2.5L

n-Pentane 99.99% HPLC – Identification of Product
Chemical Code: HPLC-P1
Chemical Name: Pentane
Chemical Grade: HPLC
Chemical Formula: CH₃(CH₂)₃CH₃
Chemical Weight: 72,15 g/mol
CAS No: 109-66-0
Chemical Synonyms: Amyl Hydride, n-Pentane, Tetrafume.

n-Pentane 99.99% HPLC – Hazards Identification
REACH No: 01-2119459286-30-XXXX
Signal Word: Danger
Supplemental Hazard Information: Repeated exposure may cause skin dryness or cracking.
Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.

n-Pentane 99.99% HPLC – Hazards statements
H225 – Highly flammable liquid and vapour.
H304 – May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H411 – Toxic to aquatic life with long lasting effects.

n-Pentane 99.99% HPLC – Precautionary statements
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 – Avoid release to the environment.
P301 + P310 + P331 – IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.

n-Pentane HPLC – Composition of Chemical
Chemical Formula: CH₃(CH₂)₃CH₃
EC No 1272/2008: 01-2119459286-30-XXXX

n-Pentane 99.99% HPLC – First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician
If: Skin Contact: Wash off with soap and plenty of water. Consult a physician.
If: Eye Contac: Flush eyes with water as a precaution.
If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available

Firefighting Measures
Extinguishing Media: Dry powder, Dry sand.
Unsuitable extinguishing media – Do NOT use water jet.
Hazards Arising: Carbon Oxides.
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: Use water spray to cool unopened containers.
Accidental Release MeasuresPersonal Precautions: Use personal protective equipment.
Avoid breathing vapours, mist or gas.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.
Enviromental Precautions: Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.
Method for Containment: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes.
Avoid inhalation of vapour or mist.
Keep away from sources of ignition – No smoking.
Take measures to prevent the build up of electrostatic charge.
Enviromental Precautions: Store in cool place.
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/Face Protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Full contact –
Material: Nitrile rubber. Minimum layer thickness: 0,4 mm.
Break through time: 480 min. Material tested: Camatril®.
Splash contact –
Material: Nitrile rubber. Minimum layer thickness: 0,4 mm.
Break through time: 480 min. Material tested: Camatril®.
Data source: KCL GmbH, Test method: EN374.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals. Flame-retardant anti-static protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination OV/AG (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Clear, colourless liquid
Odour: Benzine-like
Odour Threshold: No Data Available
pH: No Data Available
Melting Point: No Data Available
Boiling Point: 35 – 36 °C (lit).
Flash Point: -40 °C
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: Upper explosion limit: 8 %(V),
Lower explosion limit: 1,4 %(V).
Vapour pressure: 585,9 hPa at 21,13 °C
Vapour density: No Data Available
Relative density: 0,626 g/mL (25 °C)Water solubility: Insoluble
Partition Coefficien: No Data Available
Auto-ignition Temperature: 260,0 °C
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: Surface tension – ca.15,49 mN/m at 25 °C

Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: Heat, flames and sparks.
Incompatible Materials: Strong oxidizing agents
Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions – Carbon Oxides

Toxicological Information
Acute Toxicity: LD50 Oral – Rat – male and female – > 2.000 mg/kg – (OECD Test Guideline 401).
LC50 Inhalation – Rat – male and female – 4 h – > 25,3 mg/l – (OECD Test Guideline 403).
Skin Corrosion/Irritation: Rabbit –
Result: No skin irritation – 4 h
Serious Eye damage | Eye Irritation: Rabbit –
Result: No eye irritation
Cell Mutagenicity: Mutagenicity (mammal cell test): Chromosome aberration –
Chinese hamster ovary cells – Result: negative.
Ames test –
Salmonella typhimurium – Result: negative.
Mutagenicity (micronucleus test) –
Rat – male and female – Bone marrow – Result: negative
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No Data AvailableSpecific Target Organ Toxicity – Single Exposure: May cause drowsiness or dizziness – Central nervous system.
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: May be fatal if swallowed and enters airways.
Aspiration may cause Pulmonary oedema and Pneumonitis.

Ecological Information
Ecological Toxicity: Toxicity to fish:
Static test LC50 – Oncorhynchus mykiss (rainbow trout) – 4,26 mg/l – 96 h – (OECD Test Guideline 203).
Toxicity to daphnia and other aquatic invertebrates:
Static test EC50 – Daphnia magna (Water flea) – 2,7 mg/l – 48 h – Remarks: (ECHA).
Toxicity to algae:
Static test ErC50 – Selenastrum capricornutum (green algae) – 10,7 mg/l – 72 h – (OECD Test Guideline 201).
Static test NOEC – Selenastrum capricornutum (green algae) – 7,51 mg/l – 72 h (OECD Test Guideline 201).
Ecological Persistence and degradability: Biodegradability: Aerobic – Exposure time 28 d –
Result: 87 % – Readily biodegradable.
(OECD Test Guideline 301F)
Bioaccumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: Toxic to aquatic life with long lasting effects.
Avoid release to the environment.
Do not empty into drains.

Disposal Considerations
Waste Treatment Methods: Product –
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging – Dispose of as unused product.

Transport Information

UN Number: ADR/RID: 1265
IMDG: 1265
IATA: 1265
UN Shipping Hazard: ADR/RID: PENTANES
IMDG: PENTANES
IATA: Pentanes
Transport Hazard Class: ADR/RID: 3
IMDG: 3
IATA: 3
Packaging Group: ADR/RID: II
IMDG: II
IATA: II
Enviromental Hazards: ADR/RID: yes
IMDG Marine pollutant: yes
IATA: no
Special Precautions: No Data Available

Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: For this product a chemical safety assessment was not carried out
Additional Info: Contact with eyes can cause: Redness, Blurred vision, Provokes tears.
Prolonged or repeated contact with skin may cause: Defatting, Dermatitis, Central nervous system depression, Damage to the lungs.
Stomach – Irregularities – Based on Human Evidence.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
RTECS: RZ9450000

Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product

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