Ethanol 99.99% for HPLC for & Spectroscopy 2.5L

Ethanol 99.99% HPLC – Identification of Product
Chemical Code: E3303
Chemical Name: Ethanol Absolute
Chemical Grade: HPLC
Chemical Formula: C₂H₆O
Chemical Weight: 46,07 g/mol
CAS No: 64-17-5
Chemical Synonyms: Ethyl Alcohol

Ethanol 99.99% HPLC – Hazards Identification
REACH No: 01-2119457610-43-XXXX
Signal Word: Danger
Supplemental Hazard Information:
Additional Hazard Information: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Hazards statementsH225 – Highly flammable liquid and vapour.
H319 – Causes serious eye irritation.

Ethanol 99.99% HPLC – Precautionary statements
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 – Wear eye protection/ face protection.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Ethanol 99.99% HPLC – Composition of Chemical
Chemical Formula: C₂H₆O
EC No 1272/2008: 01-2119457610-43-XXXX

Ethanol 99.99% HPLC – First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Wash off with soap and plenty of water. Consult a physician.
If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth withwater. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available

Firefighting Measures
Extinguishing Media: Dry powder, Dry sand.
Do NOT use water jet.
Hazards Arising: Carbon Oxides
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: Use water spray to cool unopened containers.

Accidental Release Measures
Personal Precautions: Use personal protective equipment.
Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.
Enviromental Precautions: Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Method for Containment: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes.
Avoid inhalation of vapour or mist.
Keep away from sources of ignition – No smoking.
Take measures to prevent the build up of electrostatic charge.
Enviromental Precautions: Store in cool place.
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Hygroscopic.
Storage class (TRGS 510): Flammable liquids
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/Face Protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU
Directive 89/686/EEC and the standard EN 374 derived from it. Full contact –
Material: Butyl-rubber. Minimum layer thickness: 0,3 mm.
Break through time: 480 min. Material tested: Butoject®.
Splash contact –
Material: Nitrile rubber. Minimum layer thickness: 0,2 mm.
Break through time: 38 min. Material tested:Dermatril® P.
Data source: KCL GmbH, D-36124. Test method: EN374.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Impervious clothing. Flame retardant anti-static protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Clear, colourless liquid
Odour: No Data Available
Odour Threshold: Pungent
pH: 7,0 (10 g/l, @ 20 °C)
Melting Point: -143,99 °C
Boiling Point: 78,0 – 80,0 °C
Flash Point: 14,0 °C (closed cup)
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: Upper explosion limit: 27,7 %(V),
Lower explosion limit: 3,1 %(V).
Vapour pressure: 59,5 hPa (at 20,0 °C)
Vapour density: 1.6
Relative density: 0,7974 g/mL (at 25 °C)
Water solubility: Completely miscible
Partition Coefficien: log Pow: -0,349 at 24 °CAuto-ignition Temperature: 455 °C (at 1.013 hPa – DIN 51794)
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: No Data Available

Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: Heat, flames and sparks.
Incompatible Materials: Rubber, Various plastics, Strong oxidizing agents.
Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions – Carbon Oxides

Toxicological Information
Acute Toxicity: LD50 Oral – Rat – male and female – 10.470 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation – Rat – male and female – 4 h – 124,7 mg/l
(OECD Test Guideline 403)
Skin Corrosion/Irritation: Rabbit –
Result: No skin irritation – 24 h
(OECD Test Guideline 404)
Serious Eye damage | Eye Irritation: Rabbit –
Result: Causes serious eye irritation.
(OECD Test Guideline 405)
Cell Mutagenicity: Ames test –
Salmonella typhimurium – Result: negative.
In vitro mammalian cell gene mutation test –
mouse lymphoma cells – Result: negative – OECD Test Guideline 478.
Mouse – male –
Result: Positive results were obtained in some in vivo tests.
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available

Ecological Information
Ecological Toxicity: Toxicity to fish:
flow-through test LC50 – Pimephales promelas (fathead minnow) – 15.300 mg/l – 96 h (US-EPA).
Toxicity to daphnia and other aquatic invertebrates:
static test LC50 – Ceriodaphnia dubia (water flea) – 5.012 mg/l – 48 h – Remarks: (ECHA).
Toxicity to algae:
static test ErC50 – Chlorella vulgaris (Fresh water algae) – 275 mg/l – 72 h (OECD Test Guideline 201).
Toxicity to bacteria:
static test IC50 – activated sludge – > 1.000 mg/l – 3 h – (OECD Test Guideline 209).
Ecological Persistence and degradability: Biodegradability:
Aerobic – Exposure time 15 d – Result: ca.95 % – Readily biodegradable. – (OECD Test Guideline 301E).
Biochemical Oxygen Demand (BOD) 930 – 1.670 mg/g Remarks: (Lit.).
Theoretical oxygen demand 2.100 mg/g Remarks: (Lit.).
Bioaccumulative Potential: Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected.
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: No Data Available

Disposal Considerations
Waste Treatment Methods: Product –
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing
with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging – Dispose of as unused product.
Transport InformationUN Number: ADR/RID: 1170
IMDG: 1170
IATA: 1170
UN Shipping Hazard: ADR/RID: ETHANOL
IMDG: ETHANOL
IATA: Ethanol
Transport Hazard Class: ADR/RID: 3
IMDG: 3
IATA: 3
Packaging Group: ADR/RID: II
IMDG: II
IATA: II
Enviromental Hazards: ADR/RID: no
IMDG Marine pollutant: no
IATA: no
Special Precautions: No data available
Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: A Chemical Safety Assessment has been carried out for this substance.
Additional Info: Repeated dose toxicity –
Rat – male – Oral – No observed adverse effect level – 1.730 mg/kg – Lowest observed adverse effect level – 3.200 mg/kg.
RTECS: KQ6300000.
Irritant effects, Respiratory paralysis, Dizziness, Narcosis, Inebriation, Euphoria, Nausea, Vomiting.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product

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