Malic Acid 25kg

Product Name DL-Malic acid 25kg

Cat No. : AC125250000; AC125250010; AC125250050; AC125252500; AC125255000

1. Hazard(s) identification

CAS No 6915-15-7

Synonyms DL-Hydroxysuccinic acid

Recommended Use Laboratory chemicals.

Uses advised against Food, drug, pesticide or biocidal product use.

Details of the supplier of the safety data sheet

Company

REFLECTA LAB SUPPLIES

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious Eye Damage/Eye Irritation Category 2

Label Elements

Signal Word

Warning

Hazard Statements

Causes serious eye irritation

None identified3. Composition/Information on Ingredients 4. First-aid measures

Precautionary Statements

Prevention

Wash face, hands and any exposed skin thoroughly after handling

Wear eye/face protection

Eyes

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attention

Hazards not otherwise classified (HNOC)

Component	CAS No	Weight %
Malic acid 25kg	6915-15-7	<=100

1. Malic Acid 25kg – Fire-fighting measures

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

None reasonably foreseeable.

Most important symptoms and

effects

Notes to Physician Treat symptomatically

Suitable Extinguishing Media Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam. Unsuitable Extinguishing Media No information available

Flash Point 203 °C / 397.4 °F

Method – No information available

Autoignition Temperature 340 °C / 644 °F

Explosion Limits

Upper No data available

Lower No data available

Sensitivity to Mechanical Impact No information available

Sensitivity to Static Discharge No information available

Handling and storage

Specific Hazards Arising from the Chemical

Keep product and empty container away from heat and sources of ignition.

Hazardous Combustion Products

Carbon monoxide (CO). Carbon dioxide (CO2).

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full

protective gear.

1. Malic Acid 25kg – Exposure controls / personal protection
   

Health

Flammability

Instability

Physical hazards

2

1

0

N/A

Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust formation.

Environmental Precautions Should not be released into the environment.

Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed

Methods for Containment and Clean

Up

containers for disposal.

7.

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. IncompatibleMaterials. Bases. Metals. Reducing Agent.

Exposure Guidelines This product does not contain any hazardous materials with occupational exposure9. Physical and chemical properties

limitsestablished by the region specific regulatory bodies.

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stationsand safety showers are close to the workstation location.

Personal Protective Equipment

Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described byOSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard

EN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European StandardEN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if

exposure limits are exceeded or if irritation or other symptoms are experienced.

Handle in accordance with good industrial hygiene and safety practice.

Hygiene Measures

Physical State Solid

Appearance Off-white

Odor Odorless

Odor Threshold No information available 0. Stability and reactivity

Decomposition Temperature > 225°C – < 235°C

pH ~ 2 1% aq. solution Melting Point/Range 128 – 132 °C / 262.4 – 269.6 °F Boiling Point/Range No information available °C / °F Flash Point 203 °C / 397.4 °F Evaporation Rate Not applicable Flammability (solid,gas) No information available Flammability or explosive limits

Upper No data available Lower No data available Vapor Pressure 0.00039 Pa @ 25 °C Vapor Density Not applicable Specific Gravity 1.615 g/cm3 @20°C Bulk Density &1615 kg/m3 @ 20°C Solubility Soluble

Partition coefficient; n-octanol/water No data available Autoignition Temperature 340 °C / 644 °F Toxicological information

Viscosity Not applicable Molecular Formula C4 H6 O5 Molecular Weight 134.09

1

Reactive Hazard None known, based on information available Stability Stable under normal conditions.

Conditions to Avoid Excess heat. Incompatible products.

Incompatible Materials Bases, Metals, Reducing Agent

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11.

Acute Toxicity

Product Information

Component Information

Component	LD50 Oral	LD50 Dermal	LC50 Inhalation
Malic acid	3500 mg/kg bw (Rat)	>20000 mg/kg bw (Rabbit)	>1.306 mg/L air (analytical) 4h (Rat)

No information available

Toxicologically Synergistic

Products

Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Severe eye irritant

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component	CAS No	IARC	NTP	ACGIH	OSHA	Mexico
Malic acid	6915-15-7	Not listed	Not listed	Not listed	Not listed	Not listed

1. Malic Acid 25kg – Ecological information

Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT – single exposure None known

STOT – repeated exposure None known

Aspiration hazard No information available

No information available

Symptoms / effects,both acute and

delayed

1. Disposal considerations
   

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

1

Ecotoxicity

Do not empty into drains.

1. Malic Acid – Transport information
   

Component	Freshwater Algae	Freshwater Fish	Microtox	Water Flea
Malic acid	EC50 > 100 mg/L 72h (OECD 201)	LC50: > 100 mg/L 96h (OECD 203)	EC50 > 300mg/L 3h (OECD209)	LC50 = 240 mg/L 48h (OECD 202)

1. Malic Acid – Regulatory information

Persistence and Degradability Persistence is unlikely

Bioaccumulation/ Accumulation No information available.

Mobility Will likely be mobile in the environment due to its water solubility.

Component	log Pow
Malic acid	-1.26

1

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as ahazardous waste. Chemical waste generators must also consult local, regional, and

national hazardous waste regulations to ensure complete and accurate classification.

1

DOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG/IMO Not regulated

1

United States of America Inventory

Component	CAS No	TSCA	TSCA Inventory notification – Active-Inactive	TSCA – EPA RegulatoryFlags
Malic acid	6915-15-7	X	ACTIVE	–

Legend:

TSCA US EPA (TSCA) – Toxic Substances Control Act, (40 CFR Part 710)

X – Listed

‘-‘ – Not Listed

TSCA 12(b) – Notices of Export Not applicable

International Inventories

China, X = listed, Australia, U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (KECL), China (IECSC),Japan (ENCS), Philippines (PICCS), Japan (ISHL), Japan (ISHL).

Component	CAS No	DSL	NDSL	EINECS	PICCS	ENCS	ISHL	AICS	IECSCKECL
Malic acid	6915-15-7	X	– 230-022-8	X	X	X	X	XKE-20414

KECL – NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313 Not applicable

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act) Not applicable

Clean Air Act Not applicable

Not applicable

OSHA – Occupational Safety and

Health Administration

CERCLA Not applicable

California Proposition 65 This product does not contain any Proposition 65 chemicals. Not applicable

U.S. State Right-to-Know

Regulations

U.S. Department of Transportation

Reportable Quantity (RQ): N

DOT Marine Pollutant N

DOT Severe Marine Pollutant N

This product does not contain any DHS chemicals.

U.S. Department of Homeland

Security

Other International Regulations

Mexico – Grade No information available

Authorisation/Restrictions according to EU REACH

Safety, health and environmental regulations/legislation specific for the substance or mixture

Component	CAS No	OECD HPV	Persistent Organic Pollutant	Ozone DepletionPotential	Restriction of Hazardous Substances (RoHS)
Malic acid	6915-15-7	Listed	Not applicable	Not applicable	Not applicable

Component

CAS No

Seveso III Directive (2012/18/EC) – Qualifying Quantitiesfor Major AccidentNotification

Seveso III Directive(2012/18/EC) – Qualifying Quantitiesfor Safety Report Requirements

Rotterdam Convention (PIC)

Basel Convention(Hazardous Waste)

6. Malic Acid – Other information

DL-Malic acid Revision Date 22-06-2022

Malic acid

6915-15-7

Not applicable

Not applicable

Not applicable

Not applicable

1

Disclaimer

Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and we expressly disclaim all warranties of every kind and nature, including warranties of merchantability and fitness for a particular purpose in respect to the use or suitability of the product. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.

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