Ethanol 95/E5

1: Identification

1.1. Product identifier

Product form : Mixtures

Product name : Ethanol 95/E5

Product code : 64-17-5, 141-78-6

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : For laboratory and manufacturing use only.

1.3. Company Information

REFLECTA LABORATORY SUPPLIES

SECTION 2: Ethanol 95/E5 – Hazards identification

2.1. Classification of the substance or mixture

GHS-US classification

Flam. Liq. 3 H226

Skin Irrit. 2 H315

Eye Irrit. 2A H319

Carc. 1A H350

Repr. 2 H361

STOT SE 1 H370

Full text of H statements: see section 16

2.2. Label elements

GHS-US labeling

Hazard pictograms (GHS-US) :

Signal word (GHS-US) : Danger

Hazard statements (GHS-US) : H226 – Flammable liquid and vapor

H315 – Causes skin irritation

H319 – Causes serious eye irritation

H350 – May cause cancer

(Ingestion)

H361 – Suspected of damaging the unborn child (Ingestion)

H370 – Causes damage to organs (central nervous system, optic nerve) (oral, Dermal)

Precautionary statements (GHS-US) : P201 – Obtain special instructions before use

P202- Do not handle until all safety precautions have been read and understood

P210- Keep away from heat, hot surfaces, open flames, sparks. – No smoking

ETHANOL 95/E5

P233- Keep container tightly closed

P240- Ground/bond container and receiving equipment

P241- Use explosion-proof electrical, lighting, ventilating equipment

P242- Use only non-sparking tools

P243- Take precautionary measures against static discharge

P260- Do not breathe mist, spray, vapors

P264- Wash exposed skin thoroughly after handling

P270- Do not eat, drink or smoke when using this product

P280- Wear eye protection, face protection, protective clothing, protective gloves

P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated

clothing. Rinse skin with water/shower

P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing

P308+P313 – IF exposed or concerned: Get medical advice/attention

P332+P313 – If skin irritation occurs: Get medical advice/attention

P337+P313 – If eye irritation persists: Get medical advice/attention

P362+P364 – Take off contaminated clothing and wash it before reuse

P370+P378 – In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam to

Extinguish

P403+P235 – Store in a well-ventilated place. Keep cool

P405 – Store locked up

P501 – Dispose of contents/container to comply with local, state and federal regulations

2.3. Other hazards

Other hazards not contributing to the : None.

classification

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substances

Not applicable

Full text of H-phrases: see section 16

3.2. Ethanol 95/E5- Mixtures

Ethanol; ethyl alcohol

Contents: 95.00 %W/W

CAS-No. 64-17-5 Index-No. 603-002-00-5 EC-No. 200-578-6 Symbol(s) F R-phrase(s) -R11

Ethyl acetate

Contents: 5.00 %W/W

CAS-No. 141-78-6 Index-No. 607-022-00-5 EC-No. 205-500-4

ETHANOL 95/E5

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general

First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact

First-aid measures after ingestion

: Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim’s condition: doctor/hospital. Never give alcohol to drink.

: Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. : Rinse with water. Take victim to a doctor if irritation persists.

: Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.

: Rinse mouth with water. Do not induce vomiting. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Respiratory difficulties. Central

nervous system depression. Symptoms similar to those listed under ingestion.

Symptoms/effects after skin contact : Slight irritation.

Symptoms/effects after eye contact : Redness of the eye tissue. Lacrimation. ON CONTINUOUS EXPOSURE/CONTACT: Irritation of the eye tissue.

Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Risk of aspiration pneumonia. Red skin. Body temperature rise. Damp/clammy skin. Excited/restless. Accelerated heart action. Central

nervous system depression. Dizziness. Narcosis. Headache. Drunkenness. Nausea. Vomiting.

Disturbed motor response. Coordination disorders. Visual disturbances. Impaired

concentration. Delusions. Disturbed sensation of pain. Disturbances of heart rate. Disturbances

of consciousness. Tremor. Cramps/uncontrolled muscular contractions. Dilated pupils.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Gastrointestinal complaints. Enlargement/affection of the liver. Change in the haemogramme/blood composition. Cardiac

and blood circulation effects. High arterial pressure. Impairment of the nervous system.

Behavioural disturbances. Mental confusion. Disturbed tactile sensibility. Tremor. Affection

of the bone marrow. Affection of the endocrine system. Weakening of the immune system.

4.3. Indication of any immediate medical attention and special treatment needed

Obtain medical assistance.

SECTION 5: Ethanol 95/E5 – Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Water spray. Alcohol-resistant foam. BC powder. Carbon dioxide. Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium.

5.2. Special hazards arising from the substance or mixture

Fire hazard : DIRECT FIRE HAZARD. Highly flammable. Gas/vapor flammable with air within explosion limits. INDIRECT FIRE HAZARD. May be ignited by sparks. Gas/vapor spreads at floor level:

ignition hazard. Reactions involving a fire hazard: see “Reactivity Hazard”.

Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. may be ignited by sparks. Reactions with explosion

hazards: see “Reactivity Hazard”.

Reactivity : Upon combustion: CO and CO2 are formed. Reacts violently with many compounds e.g.: with (strong) oxidizers: (increased) risk of fire/explosion. Violent to explosive reaction with (some)

acids.

5.3. Advice for firefighters

Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat.

Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

ETHANOL 95/E5

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.

6.1.1. For non-emergency personnel

Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. See “Material-Handling” to select protective clothing.

Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or

sparks. Spark- and explosion-proof appliances and lighting equipment. Keep containers closed.

Wash contaminated clothes.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection. Avoid breathing mist, spray. Emergency procedures : Ventilate area.

6.2. Ethanol 95 – Environmental precautions

Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up

For containment : Contain released substance, pump into suitable containers. Consult “Material-handling” to select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to

reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse

combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do

not use compressed air for pumping over spills.

Methods for cleaning up : Take up liquid spill into a non combustible material e.g.: sand, earth, vermiculite or kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. See “Material

handling” for suitable container materials. Carefully collect the spill/leftovers. Damaged/cooled

tanks must be emptied. Do not use compressed air for pumping over spills. Clean

contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent

authority. Wash clothing and equipment after handling.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Ethanol 95 /E5 – Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry

the installation before use. Do not discharge the waste into the drain. Do not use compressed

air for pumping over. Use spark-/explosionproof appliances and lighting system. Take

precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from

ignition sources/sparks. Observe normal hygiene standards. Keep container tightly closed.

Measure the concentration in the air regularly. Work under local exhaust/ventilation.

Hygiene measures : Wash exposed skin thoroughly after handling.

ETHANOL 95/E5

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/…

equipment.

Storage conditions : Keep container tightly closed. Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep in fireproof place.

Incompatible products : Strong bases. Strong acids.

Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.

Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. strong acids. water/moisture. Storage area : Keep out of direct sunlight. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Provide for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank

with earthing. Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: closing. dry. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

Packaging materials : SUITABLE MATERIAL: stainless steel. aluminium. iron. copper. nickel. synthetic material. glass. MATERIAL TO AVOID: No data available.

7.3. Specific end use(s)

No additional information available

SECTION 8: Ethanol 95 – Exposure controls/personal protection

8.1. Control parameters

Ethyl Alcohol, 95% v/v

USA ACGIH	ACGIH STEL (ppm)	1000 ppm (Ethanol; USA; Short time value; TLV –
Adopted Value)
Ethanol (64-17-5)
USA ACGIH	ACGIH STEL (ppm)	1000 ppm (Ethanol; USA; Short time value; TLV –
Adopted Value)
USA OSHA	OSHA PEL (TWA) (mg/m³)	1900 mg/m³
USA OSHA	OSHA PEL (TWA) (ppm)	1000 ppm
Isopropyl Alcohol (2-Propanol) (67-63-0)
USA ACGIH	ACGIH TWA (ppm)	200 ppm (2-propanol; USA; Time-weighted average
exposure limit 8 h; TLV – Adopted Value)
USA ACGIH	ACGIH STEL (ppm)	400 ppm (2-propanol; USA; Short time value; TLV –
Adopted Value)
USA OSHA	OSHA PEL (TWA) (mg/m³)	980 mg/m³
USA OSHA	OSHA PEL (TWA) (ppm)	400 ppm

Methanol (67-56-1)
USA ACGIH	ACGIH TWA (ppm)
USA ACGIH	ACGIH STEL (ppm)
USA OSHA	OSHA PEL (TWA) (mg/m³)
USA OSHA	OSHA PEL (TWA) (ppm)

200 ppm (Methanol; USA; Time-weighted average exposure limit 8 h; TLV – Adopted Value) 250 ppm (Methanol; USA; Short time value; TLV – Adopted Value)

260 mg/m³

200 ppm

ETHANOL 95/E5

8.2.	Exposure controls
Appropriate engineering controls	: Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure. Ensure adequate ventilation.
Personal protective equipment	: Safety glasses. Gloves. Protective clothing.

Materials for protective clothing : GIVE EXCELLENT RESISTANCE: butyl rubber. viton. GIVE GOOD RESISTANCE: neoprene. tetrafluoroethylene. GIVE LESS RESISTANCE: nitrile rubber. polyethylene. GIVE POOR

RESISTANCE: natural rubber. PVA. PVC.

Hand protection : Gloves.

Eye protection : Safety glasses.

Skin and body protection : Protective clothing.

Respiratory protection : Wear gas mask with filter type A if conc. in air > exposure limit.

Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Liquid.

Molecular mass : 46.07 g/mol

Color : Colourless.

Odor : Alcohol odour. Pleasant odour.

Odor threshold : 100 ppm

188 mg/m³

pH : No data available

Relative evaporation rate (butyl acetate=1) : 2.4

Relative evaporation rate (ether=1) : 8.3

Melting point : -115 °C

Freezing point : No data available

Boiling point : 78 °C

Flash point : 25 °C

Critical temperature : 243 °C

Auto-ignition temperature : 363 °C

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : 59 hPa (20 °C)

Vapor pressure at 50 °C : 300 hPa (50 °C)

Critical pressure : 63840 hPa

Relative vapor density at 20 °C : 1.6

Relative density : No data available

Relative density of saturated gas/air mixture : 1.04

Specific gravity / density : 0.8 g/l

ETHANOL 95/E5

Solubility : Soluble in water. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in oils/fats. Soluble in methanol. Soluble in acids.

Water: Complete

Ethanol: Not applicable

Ether: Complete

Acetone: Complete

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : 0.0012 Pa.s (20 °C)

Explosive properties : No data available

Oxidizing properties : No data available

Explosion limits : 3.3 – 19.0 vol %

67 – 290 g/m³

9.2. Other information

Specific conductivity : 130000 pS/m

Saturation concentration : 112 g/m³

VOC content : 100 %

Other properties : Gas/vapour heavier than air at 20°C. Clear. Hygroscopic. Volatile. Substance has neutral reaction.

SECTION 10: Stability and reactivity

10.1. Reactivity

Upon combustion: CO and CO2 are formed. Reacts violently with many compounds e.g.: with (strong) oxidizers: (increased) risk of fire/explosion. Violent to explosive reaction with (some) acids.

10.2. Chemical stability

Hygroscopic.

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures. Open flame.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide. May release flammable gases.

ETHANOL 95/E5

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Ethanol (64-17-5)
LD50 oral rat	10740 mg/kg (Rat; Experimental value,Rat; Experimental value)

LD50 dermal rabbit > 16000 mg/kg (Rabbit; Literature study)

Isopropyl Alcohol (2-Propanol) (67-63-0)
LD50 dermal rabbit	12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit)

LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat)

Water (7732-18-5)

LD50 oral rat ≥ 90000 mg/kg

Methanol (67-56-1)
LD50 oral rat	> 5000 mg/kg (Rat; BASF test; Literature study; 1187-2769 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rabbit	15800 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l)	85 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm)	64000 ppm/4h (Rat; Literature study)

Skin corrosion/irritation : Causes skin irritation.

Serious eye damage/irritation : Causes serious eye irritation.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Based on available data, the classification criteria are not met

Carcinogenicity : May cause cancer (Ingestion).

Ethyl Alcohol, 95% v/v

IARC group

Ethanol (64-17-5)

IARC group

Isopropyl Alcohol (2-Propanol) (67-63-0)

IARC group

1 – Carcinogenic to humans 1 – Carcinogenic to humans 3 – Not classifiable

ETHANOL 95/E5

Reproductive toxicity : Suspected of damaging the unborn child (Ingestion).

Based on available data, the classification criteria are not met

Specific target organ toxicity – single exposure : Causes damage to organs (central nervous system, optic nerve) (oral, Dermal).

Specific target organ toxicity – repeated : Not classified

exposure Based on available data, the classification criteria are not met

Aspiration hazard : Not classified

Based on available data, the classification criteria are not met

Potential Adverse human health effects and : Harmful if swallowed. Based on available data, the classification criteria are not met. symptoms

Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Respiratory difficulties. Central

nervous system depression. Symptoms similar to those listed under ingestion.

Symptoms/effects after skin contact : Slight irritation.

Symptoms/effects after eye contact : Redness of the eye tissue. Lacrimation. ON CONTINUOUS EXPOSURE/CONTACT: Irritation of the eye tissue.

Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Risk of aspiration pneumonia. Red skin. Body temperature rise. Damp/clammy skin. Excited/restless. Accelerated heart action. Central

nervous system depression. Dizziness. Narcosis. Headache. Drunkenness. Nausea. Vomiting.

Disturbed motor response. Coordination disorders. Visual disturbances. Impaired

concentration. Delusions. Disturbed sensation of pain. Disturbances of heart rate. Disturbances

of consciousness. Tremor. Cramps/uncontrolled muscular contractions. Dilated pupils.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Gastrointestinal complaints. Enlargement/affection of the liver. Change in the haemogramme/blood composition. Cardiac

and blood circulation effects. High arterial pressure. Impairment of the nervous system.

Behavioural disturbances. Mental confusion. Disturbed tactile sensibility. Tremor. Affection of

the bone marrow. Affection of the endocrine system. Weakening of the immune system.

SECTION 12: Ecological information

12.1. Toxicity

Ecology – water : Not harmful to fishes (LC50(96h) >1000 mg/l). Not harmful to invertebrates (Daphnia). Slightly harmful to algae (EC50 (72h): 100 – 1000 mg/l). Harmful to plankton. Not harmful to bacteria

(EC50 >1000 mg/l). No inhibition of activated sludge.

Ethanol (64-17-5)

LC50 fish 1 14200 mg/l (LC50; US EPA; 96 h; Pimephales promelas; Flow-through system; Fresh water; Experimental value)

Isopropyl Alcohol (2-Propanol) (67-63-0)
LC50 fish 2	9640 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow through system; Fresh water; Experimental value)
EC50 Daphnia 2	13299 mg/l (EC50; Other; 48 h; Daphnia magna)

Threshold limit algae 1 > 1000 mg/l (EC50; UBA; 72 h; Scenedesmus subspicatus)

Methanol (67-56-1)
LC50 fish 1	15400 mg/l (LC50; EPA 660/3 – 75/009; 96 h; Lepomis macrochirus; Flow-through system; Fresh water; Experimental value)
EC50 Daphnia 1	> 10000 mg/l (EC50; DIN 38412-11; 48 h; Daphnia magna; Static system; Fresh water; Experimental value)

Methanol (67-56-1)
LC50 fish 2	10800 mg/l (LC50; 96 h; Salmo gairdneri)

12.2. Persistence and degradability

Ethyl Alcohol, 95% v/v

Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil.

Ethanol (64-17-5)
Persistence and degradability	Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil.
Biochemical oxygen demand (BOD)	0.8 – 0.967 g O ₂/g substance
Chemical oxygen demand (COD)	1.7 g O ₂/gtancesubs
ThOD	2.1 g O ₂/g substance

ETHANOL 95/E5

BOD (% of ThOD) 0.43

Isopropyl Alcohol (2-Propanol) (67-63-0)
Persistence and degradability	Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No test data on mobility of the substance available.
Biochemical oxygen demand (BOD)	1.19 g O ₂/g substance
Chemical oxygen demand (COD)	2.23 g O ₂/g substance

ThOD 2.4 g O ₂/g substance

Water (7732-18-5)

Persistence and degradability Not established.

Methanol (67-56-1)
Persistence and degradability	Readily biodegradable in water. Biodegradable in the soil. Highly mobile in soil.
Biochemical oxygen demand (BOD)	0.6 – 1.12 g O ₂/g substance
Chemical oxygen demand (COD)	1.42 g O ₂/g substance
ThOD	1.5 g O ce₂/g substan
BOD (% of ThOD)	0.8 (Literature study)

12.3. Bioaccumulative potential

Ethyl Alcohol, 95% v/v

BCF fish 1 1 (BCF; Other; 72 h; Cyprinus carpio; Static system; Fresh water; Read-across)

Ethanol (64-17-5)
BCF fish 1	1 (BCF; Other; 72 h; Cyprinus carpio; Static system; Fresh water; Read-across)
Log Pow	-0.31 (Experimental value)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

Isopropyl Alcohol (2-Propanol) (67-63-0)
Log Pow	0.05 (Weight of evidence approach; Other; 25 °C)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

Water (7732-18-5)

Bioaccumulative potential Not established.

Methanol (67-56-1)
BCF fish 1	< 10 (BCF; 72 h; Leuciscus idus)
Log Pow	-0.77 (Experimental value; Other)
Bioaccumulative potential	Low potential for bioaccumulation (BCF < 500).

12.4. Mobility in soil

Ethyl Alcohol, 95% v/v

Log Koc Koc,PCKOCWIN v1.66; 1; Read-across

Ethanol (64-17-5)
Surface tension	0.022 N/m (20 °C)

Log Koc Koc,PCKOCWIN v1.66; 1; Read-across

Isopropyl Alcohol (2-Propanol) (67-63-0)

Surface tension 0.021 N/m (25 °C)

Methanol (67-56-1)
Surface tension	0.023 N/m (20 °C)

ETHANOL 95/E5

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed

together if this may entail a risk of pollution or create problems for the further management of

the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or

handle hazardous waste shall take the necessary measures to prevent risks of pollution or

damage to people or animals. Recycle by distillation. Remove to an authorized waste

incinerator for solvents with energy recovery. Do not discharge into surface water. May be

discharged to wastewater treatment installation.

Additional information : LWCA (the Netherlands): KGA category 03. Hazardous waste according to Directive 2008/98/EC.

Ecology – waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1987 Alcohols, n.o.s., 3, II

UN-No.(DOT) : 1987

DOT NA no. : UN1987

Proper Shipping Name (DOT) : Alcohols, n.o.s.

Transport hazard class(es) (DOT) : 3 – Class 3 – Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 – Flammable liquid

Packing group (DOT) : II – Medium Danger

DOT Special Provisions (49 CFR 172.102) : 172 – This entry includes alcohol mixtures containing up to 5% petroleum products. IB2 – Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite

(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110

kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.

T7 – 4 178.274(d)(2) Normal…………. 178.275(d)(3)

TP1 – The maximum degree of filling must not exceed the degree of filling determined by the

following: Degree of filling = 97 / 1 + a (tr – tf) Where: tr is the maximum mean bulk temperature

during transport, and tf is the temperature in degrees celsius of the liquid during filling.

TP8 – A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when

the flash point of the hazardous material transported is greater than 0 C (32 F).

TP28 – A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used

provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous

material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the

MAWP.

DOT Packaging Exceptions (49 CFR 173.xxx) : 4b;150

DOT Packaging Non Bulk (49 CFR 173.xxx) : 202

DOT Packaging Bulk (49 CFR 173.xxx) : 242

DOT Quantity Limitations Passenger aircraft/rail : 5 L

(49 CFR 173.27)

DOT Quantity Limitations Cargo aircraft only (49 : 60 L

CFR 175.75)

DOT Vessel Stowage Location : B – (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25

passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on

passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this

section is exceeded.

Additional information

Other information : No supplementary information available.

ETHANOL 95/E5

ADR

Transport document d