Ethylol 95

1. Ethylol 95 – Identification of the substance/mixture and of the company/undertaking Trade name Ethylol 95
   
2. Hazards identification

Identification of the risks R11

Highly flammable.

Ethylol 95

raw material for aerosol propellants, printing ink additive, For industrial use only.

REFLECTA LAB SUPPLIES

1. Composition/information on ingredients

Ethanol; Ethyl alcohol

Contents: 95.20 %W/W

CAS-No. 64-17-5 Index-No. 603-002-00-5 EC-No. 200-578-6 Symbol(s) F R-phrase(s) -R11

propan-2-ol; isopropyl alcohol; isopropanol

Contents: 4.30 %W/W

CAS-No. 67-63-0 Index-No. 603-117-00-0 EC-No. 200-661-7 Symbol(s) F, Xi R-phrase(s) -R11 -R36 -R67

For the full text of the R-phrases mentioned in this Section, see Section 16.

Print Date 14.02.2012 100000001873 1/6

Safety Data Sheet Ethylol 95

1. Ethylol 95 – First aid measures

Inhalation Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration.

If symptoms persist, call a physician.

Skin contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact Rinse immediately with plenty of running water, also under the eyelids, for at least 15 minutes Remove contact lenses. If eye

irritation persists, consult a specialist.

Ingestion Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Call a physician

immediately.

1. Firefighting measures
   

Suitable extinguishing media

Specific hazards during firefighting

Special protective

equipment for firefighters

Water spray, Dry powder, Alcohol-resistant foam

Flash back possible over considerable distance. Do not allow run-off from fire fighting to enter drains or water courses.

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Further information Cool containers / tanks with water spray.

1. Accidental release measures

Personal precautions Keep people away from and upwind of spill/leak. Remove all sources of ignition. Do not breathe vapours or spray mist.

Environmental precautions

Prevent product from entering drains. Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material and dispose of as hazardous waste.

Additional advice Never return spills in original containers for re-use.

1. Handling and storage

Handling

Safe handling advice Do not breathe vapours or spray mist. Wear personal protective equipment.

Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition. Use explosion-proof equipment.

Print Date 14.02.2012 100000001873 2/6

Safety Data Sheet Ethylol 95

Storage

Requirements for storage areas and containers

Keep containers tightly closed in a cool, well-ventilated place.

1. Exposure controls/personal protection

Components with workplace control parameters

NATIONAL OCCUPATIONAL EXPOSURE LIMITS

EUROPEAN OCCUPATIONAL EXPOSURE LIMITS

Engineering measures

Provide sufficient air exchange and/or exhaust in work rooms.

Personal protective equipment

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

Hand protection Gloves suitable for permanent contact:

Material: butyl-rubber

Break through time: 4 h

Material thickness: 0.5 mm

Eye protection Safety glasses with side-shields

Skin and body protection Safety shoes, Protective suit

Hygiene measures Wash hands before breaks and immediately after handling the product.

Protective measures Wear suitable protective equipment.

1. Ethylol 95 – Physical and chemical properties

Form Liquid

State of matter Liquid; at 20 °C; 1,013 hPa

Colour Colourless

Odour Alcohol-like

pH Neutral

Melting point/range -88.5 °C

Boiling point/boiling range

78.4 °C

3/6

Safety Data Sheet Ethylol 95

Flash point 12 °C; Closed cup Autoignition temperature 363 °C

Lower explosion limit 3.3 %(V)

Upper explosion limit 19 %(V)

Density 0.791 g/cm3; 20 °C Water solubility partly miscible, Partly soluble

Solubility in other solvents

Medium: Diethylether; Completely soluble

Viscosity, dynamic 2.4 mPa.s

Relative vapour density 2.08

1. Stability and reactivity

Materials to avoid Oxidizing agents, Acids and bases

Hazardous

decomposition products

Carbon oxides

1. Ethylol 95 – Toxicological information

Acute oral toxicity Ethanol:

LD50 rat: 7,060 mg/kg; literature value

Isopropyl alcohol:

LD50 rat: 5,045 mg/kg; literature value

Isopropyl alcohol:

LD50 rabbit: 6,410 mg/kg; literature value

Acute inhalation toxicity Ethanol:

LC50 rat: 66,000 mg/l; literature value; 4 h

Isopropyl alcohol:

LC50 rat: 16,000 mg/l; literature value; 8 h

Acute dermal toxicity Ethanol:

LDLo rabbit: 20,000 mg/kg; literature value

Isopropyl alcohol:

LD50 rabbit: 12,800 mg/kg; literature value

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1. Ecological information Ecotoxicity effects

Toxicity to fish Ethanol:

Safety Data Sheet Ethylol 95

LC50 Pimephales promelas: 15,300 mg/l; 96 h; literature value

Isopropyl alcohol:

LC50 Pimephales promelas: > 6,000 mg/l; 96 h; (literature

value)

1. Ethylol 95 – Disposal considerations

Product Dispose of in accordance with local regulations.

Contaminated packaging Store containers and offer for recycling of material when in accordance with the local regulations.

1. Transport information

ADR UN number: 1170; Class: 3; Packaging group: II; F1; Description of the goods: ETHANOL

RID UN number: 1170; Class: 3; Packaging group: II; F1; Description of the goods: ETHANOL

ADNR UN number: 1170; Class: 3; Packaging group: II; F1; Description of the goods: ETHYL ALCOHOL SOLUTION

IMDG UN number: 1170; Class: 3; EmS: F-E, S-D; Packaging group: II; Description of the goods: ETHANOL

ICAO/IATA UN number : 1170; Class: 3; Packaging group: II; Description of the goods: Ethanol

Further information IMO Shipping name:Noxious Liquid,(11), n.o.s.( ETHYLOL 95, contains Ethyl Alcohol), Cat.Z

1. Ethylol 95 – Regulatory information

Labelling

Print Date 14.02.2012 100000001873 5/6

Safety Data Sheet Ethylol 95

Regulatory base 1999/45/EC

Symbol(s) F: Highly flammable

R-phrase(s) R11: Highly flammable.

S-phrase(s) S 9: Keep container in a well-ventilated place. S16: Keep away from sources of ignition – No smoking.

S23: Do not breathe gas/fumes/vapour/spray.

S33: Take precautionary measures against static discharges.

S36: Wear suitable protective clothing.

S60: This material and its container must be disposed of as

hazardous waste.

S 3/7: Keep container tightly closed in a cool place.

1. Other information

Full text of R-phrases referred to under sections 2 and 3

R11 Highly flammable.

R36 Irritating to eyes.

R67 Vapours may cause drowsiness and dizziness.

DisclaimerThe information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.

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