Petroleum Ether 40-60 – 25l

Petroleum Ether 40-60 25l – Identification of Product
Chemical Code: CHE-P4
Chemical Name: Petroleum Ether 40-60
Chemical Grade: AR
Chemical Formula: No Data Available
Chemical Weight:
CAS No: 64742-49-0
Chemical Synonyms: Petroleum Benzine

Petroleum Ether 40-60 25l – Hazards Identification
REACH No: No Data Available
Signal Word: Danger
Supplemental Hazard Information:
Additional Hazard Information: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.

Petroleum Ether 40-60 25l – Hazards statements
H225 – Highly flammable liquid and vapour.
H304 – May be fatal if swallowed and enters airways.
H315 – Causes skin irritation.
H336 – May cause drowsiness or dizziness.
H411 – Toxic to aquatic life with long lasting effects.

Petroleum Ether 40-60 – Precautionary statements
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 – Avoid release to the environment.
P301 + P310 + P331 – IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
P370 + P378 – In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P391 – Collect spillage.

Petroleum Ether 40-60 25l – Composition of Chemical
Chemical Formula: No Data Available
EC No 1272/2008: No Data Available

First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: Move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Wash off with soap and plenty of water.
If: Eye Contac: Rinse out with plenty of water. Remove contact lenses.
If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: Irritant effects, Respiratory paralysis, Drowsiness, Dizziness, Unconsciousness, Agitation, Spasms, Circulatory collapse, Headache, Somnolence.
Repeated exposure may cause skin dryness or cracking.
Immediate Medical Attention: No Data Available

Firefighting Measures
Extinguishing Media: Suitable extinguishing media: Dry powder, Dry sand.
Do NOT use water jet.
Hazards Arising: Carbon Oxides.
Flash back possible over considerable distance.
Container explosion may occur under fire conditions.
Advice for Firefighters: In the event of fire, wear self-contained breathing apparatus.
Info for Firefighting: Use water spray to cool unopened containers.

Accidental Release Measures
Personal Precautions: Use personal protective equipment.
Avoid breathing vapours, mist or gas.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.
Enviromental Precautions: Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.
Method for Containment: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes.
Avoid inhalation of vapour or mist.
Keep away from sources of ignition – No smoking.
Take measures to prevent the build up of electrostatic charge.
Enviromental Precautions: Store in cool place..
Keep container tightly closed in a dry and well-ventilated place.
Keep away from heat and sources of ignition.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/Face Protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Full contact –
Material: Nitrile rubber. Minimum layer thickness: 0,11 mm.
Break through time: 480 min. Material tested: Dermatril®.
Splash contact –
Material: Nitrile rubber. Minimum layer thickness: 0,11 mm.
Break through time: 480 min. Material tested: Dermatril®.
Data source: KCL GmbH, D-36124. Test method: EN374.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals. Flame retardant anti-static protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Clear, Colourless, volatile liquid
Odour: Benzine-like
Odour Threshold: No Data Available
pH: No Data Available
Melting Point: No Data Available
Boiling Point: 40 – 60 °C at 1,013 hPa
Flash Point: No Data Available
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: Upper explosion limit 7 %(V),
Lower explosion limit 1 %(V).
Vapour pressure: ? 2400 hPa at 37,8 °C
Vapour density: No Data Available
Relative density: No Data Available
Water solubility: Practically immiscible
Partition Coefficien: No Data Available
Auto-ignition Temperature: 280 – 470 °C at 1.013,25 hPa.
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: Not explosive, In use may form flammable/explosive vapour-air mixture.
Oxidizing properties: No Data Available
Other Safety Info: No Data Available

Stability and Reactivity
Reactivity: Vapours may form explosive mixture with air.
Chemical Stability: The product is chemically stable under standard ambient conditions (room temperature).
Possibility of hazardous reactions: Violent reactions possible with strong oxidizing agents.
Conditions to Avoid: Heat, flames and sparks.
Incompatible Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions – Carbon Oxides

Toxicological Information
Acute Toxicity: LD50 Oral – Rat – male and female – > 5.000 mg/kg.
LC50 Inhalation – Rat – 4 h – 54 mg/l.
LD50 Dermal – Rabbit – 4.000 mg/kg.
Skin Corrosion/Irritation: Rabbit –
Result: Irritating to skin. – 4 h
(OECD Test Guideline 404)
Serious Eye damage | Eye Irritation: Rabbit –
Result: No eye irritation
(OECD Test Guideline 405)
Cell Mutagenicity: In vitro assay:
S. typhimurium – Result: negative.
Rat – male and female:
Result: negative
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available

Ecological Information
Ecological Toxicity: Toxicity to fish:
Semi-static test LC50 – Pimephales promelas (fathead minnow) – 11 mg/l – 96 h.
Ecological Persistence and degradability: Biodegradability:
Aerobic – Exposure time 28 d –
Result: 77,05 % – Readily biodegradable.
(OECD Test Guideline 301F)
Bioaccumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: Very toxic to aquatic life with long lasting effects.

Disposal Considerations
Waste Treatment Methods: Product –
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing
with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging – Dispose of as unused product.

Transport Information
UN Number: ADR/RID: 1268
IATA: 1268
IMDG: 1268
UN Shipping Hazard: ADR/RID: PETROLEUM DISTILLATES, N.O.S.
IMDG: PETROLEUM DISTILLATES, N.O.S. (Hydrocarbon mixture C5-C8 Aliphates)
IATA: Petroleum distillates, n.o.s.
Transport Hazard Class: ADR/RID: 3
IATA: 3
IMDG: 3
Packaging Group: ADR/RID: II
IATA: II
IMDG: II
Enviromental Hazards: ADR/RID: Yes
IATA: Yes
IMDG: Yes
Special Precautions: No Data Available

Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: For this product a chemical safety assessment was not carried out..
Additional Info: It generally applies for Aliphatic Hydrocarbons with 6 – 18 carbon atoms:
* They may cause Pneumonia.
* In some cases also Pulmonary Oedema.
Repeated dose toxicity – Rat – male and female – inhalation (vapour).
After absorption: Headache, Dizziness, Agitation, Spasms, Unconsciousness.
Respiratory paralysis and Circulatory collapse cannot be excluded.
After absorption of very large quantities: narcosis.
Other dangerous properties can not be excluded.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Handle in accordance with good industrial hygiene and safety practice.
RTECS: Not available

DisclaimerThe information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.

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