Manganese Dioxide AR – 500g

Manganese Dioxide AR – Identification of Product
Chemical Code: CHE-M7
Chemical Name: Manganese Dioxide
Chemical Grade: AR
Chemical Formula: MnO₂
Chemical Weight: 86,94 g/mol
CAS No: 1313-13-9
Chemical Synonyms: Manganese(IV) Oxide

Manganese Dioxide AR – Hazards Identification
REACH No: No Data Available
Signal Word: Warning
Supplemental Hazard Information:
Additional Hazard Information: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.

Manganese Dioxide AR – Hazards statements
H302 + H332 – Harmful if swallowed or if inhaled.
H373 – May cause damage to organs (Brain) through prolonged or repeated exposure if inhaled.

Manganese Dioxide AR – Precautionary statements
P260 – Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 – Wash skin thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P314 – Get medical advice/ attention if you feel unwell.
P501 – Dispose of contents/ container to an approved waste disposal plant.

Manganese Dioxide AR – Composition of Chemical
Chemical Formula: MnO₂
EC No 1272/2008: No Data Available

First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: Move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Wash off with soap and plenty of water. Consult a physician.
If: Eye Contac: Flush eyes with water as a precaution.
If: Swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available

Firefighting Measures
Extinguishing Media: Use Water spray, Alcohol-resistant foam, Dry chemical or Carbon Dioxide.
Hazards Arising: Manganese/Manganese Oxides
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: No Data Available

Accidental Release Measures
Personal Precautions: Use personal protective equipment.
Avoid dust formation.
Avoid breathing vapours, mist or gas.
Ensure adequate ventilation.
Avoid breathing dust.
Enviromental Precautions: Do not let product enter drains.
Method for Containment: Pick up and arrange disposal without creating dust.
Sweep up and shovel.
Keep in suitable, closed containers for disposal.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
Enviromental Precautions: Store in cool place.
Keep container tightly closed in a dry and well-ventilated place.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/Face Protection: Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Full contact – Material: Nitrile rubber. Minimum layer thickness: 0,11 mm
Break through time: 480 min. Material tested: Dermatril®
Splash contact – Material: Nitrile rubber. Minimum layer thickness: 0,11 mm
Break through time: 480 min. Material tested: Dermatril®
Data source: KCL GmbH, D-36124. Test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Grey to Black, crystals, powder or granules
Odour: Odourless
Odour Threshold: No Data Available
pH: No Data Available
Melting Point: Melting point/range: 535 °C
Boiling Point: No Data Available
Flash Point: No Data Available
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: No Data Available
Vapour pressure: No Data Available
Vapour density: No Data Available
Relative density: No Data Available
Water solubility: 0,001 g/l at 20 °C
Partition Coefficien: No Data Available
Auto-ignition Temperature: No Data Available
Decomposition Temperature: ca. 535 °C
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: No Data Available

Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: No Data Available
Incompatible Materials: Strong acids, Strong reducing agents, Organic materials
Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions – Manganese / Manganese Oxides.

Toxicological Information
Acute Toxicity: No Data Available
Skin Corrosion/Irritation: Rabbit –
Result: No skin irritation – 4 h
(OECD Test Guideline 404)
Serious Eye damage | Eye Irritation: Rabbit –
Result: No eye irritation – 72 h
(OECD Test Guideline 405)
Cell Mutagenicity: No Data Available
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: Inhalation – May cause damage to organs through prolonged or repeated exposure – Brain.
Aspiration Hazard: No Data Available

Ecological Information
Ecological Toxicity: No Data Available
Ecological Persistence and degradability: No Data Available
Bioaccumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: No Data Available

Disposal Considerations
Waste Treatment Methods: Product –
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste.
Contaminated packaging – Dispose of as unused product.

Transport Information
UN Number: ADR/RID: –
IMDG: –
IATA: –
UN Shipping Hazard: ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport Hazard Class: ADR/RID: –
IMDG: –
IATA: –
Packaging Group: ADR/RID: –
IMDG: –
IATA: –
Enviromental Hazards: ADR/RID: no
IMDG Marine pollutant: no
IATA: no
Special Precautions: No data available

Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: For this product a chemical safety assessment was not carried out
Additional Info: Men exposed to Manganese dusts showed a decrease in fertility.
Chronic Manganese poisoning primarily involves the central nervous system.
Early symptoms include languor, sleepiness and weakness in the legs.
A stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall in walking are findings in more advanced cases.
High incidence of pneumonia has been found in workers exposed to the dust or fume of some Manganese compounds.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Liver – Irregularities – Based on Human Evidence
RTECS: OP0350000

Disclaimer

The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.

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