Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid)

Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Product identifier
Trade name: LINEAR ALKYL BENZENE SULPHONIC ACID (96% SULPHONIC ACID)

1 Identification
2 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Hazard(s) identification
· Classification of the substance or mixture
Harmful if swallowed.
Causes severe skin burns and eye damage.
Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
·
Signal word Danger
· Hazard statements
·
Harmful if swallowed.
·
Causes severe skin burns and eye damage.
·
Toxic to aquatic life.
·
Harmful to aquatic life with long lasting effects.
· Precautionary statements
Avoid release to the environment.
Wear protective gloves / protective clothing / eye protection / face protection.
If swallowed: Call a poison center / doctor if you feel unwell.
If on skin: Wash with plenty of water. Call a poison center / doctor if you feel unwell.
If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If exposed or concerned: Call a poison center / doctor
· Classification system:
·
NFPA ratings (scale 0 – 4)
·
Other hazards
·
Results of PBT and vPvB assessment
·
PBT: Not applicable.
·
vPvB: Not applicable.

3Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
Description of first aid measures
General information:
First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
After inhalation: Fresh air. Call in physician.
After skin contact: Take off immediately all contaminated clothing. Rinse skin with water / shower. Call a physician immediately.
After eye contact:
Rinse out with plenty of water. Immediately call in ophthalmologist.
After swallowing: Immediately make person drink water (two glases at most). Consult a physician.
Information for doctor:
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Extinguishing media
Suitable extinguishing agents:
Water fog, Foam, Carbon Dioxide (CO2), Dry chemical powder.
Special hazards arising from the substance or mixture
Material is not flammable but if involved in a fire could give off toxic fumes such as Sulphur dioxide.
Advice for firefighters: Stay in danger area only with self-contained breathing apparatus.
Protective equipment: Mouth respiratory protective device.
· Personal precautions, protective equipment and emergency procedures
Avoid breathing (vapour, mist, spray).
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· Substances:
CAS: 85536-14-7 Alkyl benzene sulphonic acid (C₁₀-C₁₆) ˃ 90 – 98
CAS: 67774-74-7 Alkyl benzene (C₁₀-C₁₆) 2 – < 3
CAS: 7664-93-9 Sulfuric Acid 1 – < 3
4 First-aid measures
5 Fire-fighting measures

6 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Accidental release measures
Environmental precautions:
Avoid release to the environment.
Prevent any leakage or spillage if safe to do so.
Methods and material for containment and cleaning up:
Prevent entry into waterways, sewers, basement or confined space.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
Protective Action Criteria for Chemicals

7 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Handling and storage
Handling: Do not inhale substance/mixture.
Precautions for safe handling
Avoid skin, eye and clothing contact.
Wash hands thoroughly after handling.
Ensure good ventilation/exhaustion at the workplace. Open and handle with care.
Information about protection against explosions and fires:
Keep ignition sources away – Do not smoke.
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage: Store in original tightly closed container.
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s) No further relevant information available.

8 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Exposure controls/personal protection
· Additional information about design of technical systems: No further data; see section 7.
· Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed. Immediately
remove all soiled and contaminated clothing. Wash hands
before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use respiratory protective device that is independent of
circulating air.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the
product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion
and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product
is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
· The exact break through time has to be found out by the manufacturer of the protective
gloves and has to be observed.
· Eye protection:
· Body protection: Protective work clothing

9 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Color: Brown
· Odor: Not determined.
· Odor threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting / Freezing Point:
Boiling point/Boiling range:
6.35℃
189°C
· Flash point: 196.9 to 206.9℃ (Pensky-Martens Closed Cup)
· Flammability (solid, gaseous): Not applicable.
· Molecular Weight: Not applicable.
· Decomposition temperature: Not determined.
· Ignition temperature: Not applicable.
· Danger of explosion: Not applicable.
· Vapor pressure: Not applicable.
· Vapor Density:
· Relative density
· Density
· Evaporation rate
Estimated lighter than air.
Not determined.
1.04 g/cmᵌ
Not determined.
· Solubility in / Miscibility with
Water:
Miscible (˃16g/100g)
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Kinematic:
< 5000 CP@25℃ Typical
Not determined.
Not determined.
· Viscosity: 1200 Cp @ 25℃

10 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Stability and reactivity
Reactivity No further information available.
Chemical stability: Stable under normal conditions of use, storage and transportation.
Thermal decomposition / conditions to be avoided: No data available.
Possibility of hazardous reactions Hazardous polymerization will not occur under conditions of normal use.
Conditions to avoid Direct sunlight, extremely high or low temperatures, contact with incompatible materials.
Incompatible materials: Reactive with metals, oxides and carbonates. Generate hazardous reaction with hydroxides.
Hazardous decomposition products: Generally SO₂ is present and in some circumstances can form H₂S. Generates heat on dilution with water.

11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Causes severe skin burns. May be harmful in contact with skin.
on the eye: Causes serious eye damage.
Ingestion: Harmful if swallowed.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant to skin and serious eye damage.
· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

14 Linear Alkyl Benzene Sulponic Acid (96% Sulphonic Acid) – Transport information
· UN-Number
· DOT, IMDG, IATA UN2586
· UN proper shipping name
· DOT
· IMDG, IATA Alkyl sulphonic acids, liquid
· Waste treatment methods
No data available.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agent: Water, if necessary with cleansing agents.

13 Disposal considerations
Toxicity: to fish, to daphnia and other aquatic invertebrates, to algae.
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behavior in environmental systems:
Bio accumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow product to reach drains.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.

12 Ecological information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
(Contd. on page 10)
15 Regulatory information
· Transport hazard class(es)
· DOT
OClass 8
· IMDG, IATA
.Class 8
· Packing group
IMDG, IATA III
· Environmental hazards: Yes
· Marine pollutant: No
· Special precautions for user Read safety instructions and SDS before handling.
· Hazard identification number (Kemler code):
· EMS Number:
· Stowage Category
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations Not applicable
· IMDG
· Limited quantities (LQ) Not applicable
· Excepted quantities (EQ) Not applicable
· · UN “Model Regulation”: UN2586, Alkyl sulphonic acids, liquid
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
None of the ingredients is listed.
· Hazardous Air Pollutants
None of the ingredients is listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
·
Hazard pictograms
·
Signal word Danger
· Hazard statements
·
Harmful if swallowed.
·
Causes severe skin burns and eye damage.
·
Toxic to aquatic life.
·
Harmful to aquatic life with long lasting effects.

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing SDS: Environment protection department.
Date of preparation / last revision
Creation date for SDS: 14/08/2024
Revision 1.0, 27/02/2025: Reviewed SDS for accuracy. STN/GW

16 Other information
Precautionary statements
· Avoid release to the environment.
· Wear protective gloves / protective clothing / eye protection / face protection.
· If swallowed: Call a poison center / doctor if you feel unwell.
· If on skin: Wash with plenty of water. Call a poison center / doctor if you feel unwell.
· If in eyes: Rinse cautiously with water for several minutes.
· Remove contact lenses, if present and easy to do. Continue rinsing.
· If exposed or concerned: Call a poison center / doctor
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*

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