Ferric Sulphate Hydrate AR

Ferric Sulphate Hydrate AR – Identification of Product
Chemical Code: CHE-F75
Chemical Name: Ferric Sulphate Hyd
Chemical Grade: AR
Chemical Formula: Fe₂O₁₂S₃ · xH₂O
Chemical Weight: 399,88 g/mol
CAS No: 15244-10-7
Chemical Synonyms: Ferric Sulfate

Ferric Sulphate Hydrate AR – Hazards Identification
REACH No: No Data Available
Signal Word: Danger
Supplemental Hazard Information:
Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.

Ferric Sulphate Hydrate AR – Hazards statements
H290 – May be corrosive to metals.
H302 – Harmful if swallowed.
H315 – Causes skin irritation.
H318 – Causes serious eye damage.

Ferric Sulphate Hydrate AR – Precautionary statements
P280 – Wear eye protection/ face protection.
P301 + P312 + P330 – IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
P305 + P351 + P338 + P310 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.

Ferric Sulphate Hydrate AR – Composition of Chemical
Chemical Formula: Fe₂O₁₂S₃ · xH₂O
EC No 1272/2008: No Data Available

First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Wash off with soap and plenty of water. Consult a physician.
If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If: Swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available

Ferric Sulphate Hydrate AR – Firefighting Measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Hazards Arising: Sulphur oxides, Iron oxides.
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: No Data Available

Accidental Release Measures
Personal Precautions: Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental Precautions: Do not let product enter drains.
Method for Containment: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
Environmental Precautions: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Hygroscopic Light sensitive. Storage class (TRGS 510): Non Combustible Solids.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the
end of workday.
Eye/Face Protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable
laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested: Dermatril® (KCL 740 / Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested: Dermatril® (KCL 740 / Size M)
data source: KCL GmbH, D-36124 test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE
approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Pale Violet to Greyish White deliquescent crystals
Odour: No Data Available
Odour Threshold: No Data Available
pH: Acidic
Melting Point: No Data Available
Boiling Point: No Data Available
Flash Point: Not Applicable
Evaporation: No Data Available
Flammability: The product is not flammable.
Upper/Lower Flammability or Explosive Limits: No Data Available
Vapour pressure: No Data Available
Vapour density: No Data Available
Relative density: ca.3,1 g/cm3
Water solubility: soluble
Partition Coefficien: No Data Available
Auto-ignition Temperature: Does not ignite
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: The substance or mixture is not classified as oxidizing.
Other Safety Info: No Data Available

Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: Avoid moisture. Light.
Incompatible Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Other decomposition products – No Data Available

Toxicological Information
Acute Toxicity: LD50 Oral – Rat – > 500 – < 2.000 mg/kg (OECD Test Guideline 401)
Skin Corrosion/Irritation: Irritating to skin and Risk of serious damage to eyes.
Serious Eye damage | Eye Irritation: No Data Available
Cell Mutagenicity: No Data Available
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available

Ecological Information
Ecological Toxicity: Harmful to fish. Information given is based on data on the components and the ecotoxicology of similar products.
Toxicity to daphnia and other aquatic invertebrates
Remarks: Harmful to aquatic organisms. Information given is based on data on the components and the ecotoxicology of similar products.
Ecological Persistence and degradability: The methods for determining biodegradability are not applicable to inorganic substances.
Bio-accumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: No Data Available

Disposal Considerations
Waste Treatment Methods: Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging
Dispose of as unused product

Transport Information
UN Number: ADR/RID: 3260
IMDG: 3260
IATA: 3260
UN Shipping Hazard: ADR/RID: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Diiron tris(sulphate) hydrate, Sulfuric acid)
IMDG: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Diiron tris(sulphate) hydrate, Sulfuric acid)
IATA: Corrosive solid, acidic, inorganic, n.o.s. (Diiron tris(sulphate) hydrate, Sulfuric acid)
Transport Hazard Class: ADR/RID: 8
IMDG: 8
IATA: 8
Packaging Group: ADR/RID: III
IMDG: III
IATA: III
Environmental Hazards: ADR/RID: no
IMDG Marine pollutant: no
IATA: no
Special Precautions: No Data Available

Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 453/2010.
Chemical Safety Assessment: For this product a chemical safety assessment was not carried out.
Additional Info: RTECS: NO8520000
Overdose of iron compounds may have a corrosive effect on the gastrointestinal mucosa and be followed by necrosis, perforation, and stricture formation. Several hours may elapse before symptoms that can include epigastric pain, diarrhea, vomiting, nausea, and hematemesis occur. After apparent recovery a person may experience metabolic acidosis, convulsions, and coma hours or days later. Further complications may develop leading to acute liver necrosis that can result in death due to hepatic coma. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Disclaimer
The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.
Page 7 | Revised Date : 2018-08-27

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