Copper Sulphate Industrial Grade – 25kg

Copper Sulphate Industrial Grade – Identification of Product
Chemical Code: CHE-C20
Chemical Name: Cupric Sulphate Pentahydrate
Chemical Grade: Industrial Grade
Chemical Formula: CuSO₄ · 5H₂O
Chemical Weight: 249,69 g/mol
CAS No: 7758-99-8
Chemical Synonyms: Blue Vitriol,
Copper(II) Sulphate Pentahydrate,
Copper Sulphate Pentahydrate.

Copper Sulphate Industrial Grade – Hazards Identification
REACH No: No Data Available
Signal Word: Warning
Supplemental Hazard Information:
Additional Hazard Information: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.

Copper Sulphate Industrial Grade – Hazards statements
H302 – Harmful if swallowed.
H315 – Causes skin irritation.
H319 – Causes serious eye irritation.
H410 – Very toxic to aquatic life with long lasting effects.

Copper Sulphate Industrial Grade – Precautionary statements
P273 – Avoid release to the environment.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P501 – Dispose of contents/ container to an approved waste disposal plant.

Copper Sulphate Industrial Grade – Composition of Chemical
Chemical Formula: CuSO₄ · 5H₂O
EC No 1272/2008: No Data Available

First Aid Measures
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If: Skin Contact: Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If: Swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Important Symptoms: The most important known symptoms and effects are described in the labeling section.
Immediate Medical Attention: No Data Available

Firefighting Measures
Extinguishing Media: Use Water spray, Alcohol-resistant foam, Dry chemical or Carbon Dioxide.
Hazards Arising: Sulphur Oxides, Copper Oxides.
Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Info for Firefighting: No Data Available

Accidental Release Measures
Personal Precautions: Wear respiratory protection.
Avoid dust formation.
Avoid breathing vapours, mist or gas.
Ensure adequate ventilation.
Evacuate personnel to safe areas.
Avoid breathing dust.
Enviromental Precautions: Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.
Method for Containment: Pick up and arrange disposal without creating dust.
Sweep up and shovel.
Keep in suitable, closed containers for disposal.

Handling and Storage
Personal Precautions: Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
Enviromental Precautions: Store in cool place.
Keep container tightly closed in a dry and well-ventilated place.
Air sensitive.
Hygroscopic.
Handle and store under inert gas.
Storage class (TRGS 510): Non Combustible Solids.
Exposure Controls | Personal Protection
Derived No Effect Level (DNEL)
Workers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Consumers | Application Area | Exposure Routes | Health Effect | Value
No Data Available
Predicted No Effect Concentration (PNEC)
No Data Available
Engineering Controls: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Eye/Face Protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU
Directive 89/686/EEC and the standard EN 374 derived from it.
Full contact –
Material: Nitrile rubber. Minimum layer thickness: 0,11 mm.
Break through time: 480 min. Material tested: Dermatril®.
Splash contact –
Material: Nitrile rubber. Minimum layer thickness: 0,11 mm.
Break through time: 480 min. Material tested: Dermatril®.
Data source: KCL GmbH, D-36124. Test method: EN374.
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical and Chemical Properties
Appearance: Blue or Ultramarine crystals, granules or powder
Odour: No Data Available
Odour Threshold: No Data Available
pH: 3,7 – 4,5 at 50 g/l at 25 °C
Melting Point: Melting point/range: 110 °C (dec).
Boiling Point: No Data Available
Flash Point: No Data Available
Evaporation: No Data Available
Flammability: No Data Available
Upper/Lower Flammability or Explosive Limits: No Data Available
Vapour pressure: 9,7 hPa at 25 °C
Vapour density: No Data Available
Relative density: 2,284 g/cm3
Water solubility: Soluble
Partition Coefficien: No Data Available
Auto-ignition Temperature: No Data Available
Decomposition Temperature: No Data Available
Viscosity: No Data Available
Explosive properties: No Data Available
Oxidizing properties: No Data Available
Other Safety Info: No Data Available

Stability and Reactivity
Reactivity: No Data Available
Chemical Stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: No Data Available
Conditions to Avoid: Exposure to moisture.
Incompatible Materials: Powdered Metals, Anhydrous Copper(II) Sulphate.
Reacts violently with: Hydroxylamine, Magnesium.
Hazardous Decomposition Products: No Data Available

Toxicological Information
Acute Toxicity: LD50 Oral – Rat – 482 mg/kg – (OECD Test Guideline 401)
Remarks: Anhydrous
LD50 Dermal – Rat – > 2.000 mg/kg – Remarks: Anhydrous
Skin Corrosion/Irritation: Irritating to skin
Serious Eye damage | Eye Irritation: Irritating to eyes.
Cell Mutagenicity: No Data Available
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: No Data Available
Specific Target Organ Toxicity – Single Exposure: No Data Available
Specific Target Organ Toxicity – Repeated Exposure: No Data Available
Aspiration Hazard: No Data Available

Ecological Information
Ecological Toxicity: Toxicity to daphnia and other aquatic invertebrates:
EC50 – Daphnia magna (Water flea) – 0,024 mg/l – 48 h
Ecological Persistence and degradability: The methods for determining the biological degradability are not applicable to inorganic substances.
Bioaccumulative Potential: No Data Available
Mobility in Soil: No Data Available
Results of PBT and vPvB Assessment: This substance contains no components considered to be either persistent, bio-accumulative and toxic (PBT), or very persistent and very bio-accumulative (vPvB) at levels of 0.1% or higher.
Other Adverse Effect: Very toxic to aquatic life with long lasting effects.

Disposal Considerations
Waste Treatment Methods: Product –
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging – Dispose of as unused product.

Transport Information
UN Number: ADR/RID: 3077
IMDG: 3077
IATA: 3077
UN Shipping Hazard: ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper Sulphate
Pentahydrate)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper Sulphate Pentahydrate)
IATA: Environmentally hazardous substance, solid, n.o.s. (Copper Sulphate Pentahydrate)
Transport Hazard Class: ADR/RID: 9
IMDG: 9
IATA: 9
Packaging Group: ADR/RID: III
IMDG: III
IATA: III
Enviromental Hazards: ADR/RID: yes
IMDG Marine pollutant: yes
IATA: yes
Special Precautions: No Data Available
Regulatory Information
Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment: For this product a chemical safety assessment was not carried out.
Additional Info: To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
RTECS: GL8900000

Disclaimer

The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.

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